Answer:
Explanation:
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The following mechanism has been proposed for the gas-phase reaction of chloroform (CHCl3) and chlorine.Cl2 ⇌ 2Cl (fast, reversible) Cl + CHCl3 → HCl + CCl3 (slow) Cl + CCl3 → CCl4 (fast) What rate law does this mechanism predict?A)kG) [CHCl3]1/2M) [CCl3]2B) [Cl2]H) [CCl3]1/2N) [HCl]2C) [Cl]I) [HCl]1/2O) [Cl2]2D) [CHCl3]J) [Cl2]1/2P) [Cl]2E) [CCl3]K) [Cl]1/2 F) [HCl]L) [CHCl3]2
The following mechanism has been proposed for the gas-phase reaction of chloroform (CHCl3) and chlorine.Cl2 ⇌ 2Cl (fast, reversible) Cl + CHCl3 → HCl + CCl3 (slow) Cl + CCl3 → CCl4 (fast) What rate law does this mechanism predict?A)kG) [CHCl3]1/2M) [CCl3]2B) [Cl2]H) [CCl3]1/2N) [HCl]2C) [Cl]I) [HCl]1/2O) [Cl2]2D) [CHCl3]J) [Cl2]1/2P) [Cl]2E) [CCl3]K) [Cl]1/2 F) [HCl]L) [CHCl3]2
Question
Asked Oct 30, 2019
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The following mechanism has been proposed for the gas-phase reaction of chloroform (CHCl3) and chlorine.
Cl2 ⇌ 2Cl (fast, reversible)
Cl + CHCl3 → HCl + CCl3 (slow)
Cl + CCl3 → CCl4 (fast)
What rate law does this mechanism predict?
A)k G) [CHCl3]1/2 M) [CCl3]2
B) [Cl2] H) [CCl3]1/2 N) [HCl]2
C) [Cl] I) [HCl]1/2 O) [Cl2]2
D) [CHCl3] J) [Cl2]1/2 P) [Cl]2
E) [CCl3] K) [Cl]1/2
F) [HCl] L) [CHCl3]2
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Expert Answer
Step 1
The three step mechanism of the given reaction is,
CL2 dissociate to give chorine a fast and reverse reaction.
React with CHCL3 to give HCL and CCL3 a slow reaction
React with CL to give CCL4.
Step 2
Add equation (1), (2), and (3) to get the overall reaction.
The overall reaction is expressed as,
CL2 dissociate to give chorine a fast and reverse reaction.
React with CHCL3 to give HCL and CCL3 a slow reaction
React with CL to give CCL4.
Step 3
The chlorine atom produced in equation (1) is consumed in equation (3) and CCl3 a molecule is produced in equation (2) is consumed in equation (3).
CL react with CHCL3 to give a reversible reaction of HCL and CCL4.
Yellow
Green
Blue
Answer:
Explanation:
Red is diffracted the most due to its long wavelength. Compared to violet which is the shortest and is diffracted the least.
Each shift worked can pay for 3.75 loads of laundry if each load costs 16 quarters.
This problem can be solved using simple dimensional analysis. The steps are:
STEP 1: Sort first the given in the problem to identify possible conversion factors to be used in the dimensional analysis.
The following equalities are given in the problem:
STEP 2: From these equalities, the following dimensional analysis can be set up:
Therefore, one shift can pay for 3.75 loads of laundry.
Keywords: dimensional analysis, problem solving
H3O+
Cl-
Cs+
OH-
Answer:
Explanation:
B.) negative enthalpy change and negative entropy change
C.) positive enthalpy change and negative entropy change
D.) negative enthalpy change and positive entropy change
Answer: B.) negative enthalpy change and negative entropy change
Explanation:
According to Gibb's equation:
= Gibbs free energy
= enthalpy change
= entropy change
T = temperature in Kelvin
= +ve, reaction is non spontaneous
= -ve, reaction is spontaneous
= 0, reaction is in equilibrium
Thus when = -ve
= -ve
only at low temperature
Reaction is spontaneous only if temperature is low.
Answer:
1.6 atm
Explanation:
We are given that total pressure of mixture of two gases=5.7 atm
Partial pressure of one gas=4.1 atm
We have to find the partial pressure of other branch.
We know that Dalton;s law of partial pressure
It states that pressure exerted by mixture of gases is equal to sum of partial pressure exerted by gases in mixture.
Let x bet the pressure exert by other gas
Apply this law
Total pressure=4.1+x
Hence, the partial pressure of other gas=1.6 atm.