Which of the following circumstances will result in a reaction that is spontaneous only at low temperatures?A.) positive enthalpy change and positive entropy change
B.) negative enthalpy change and negative entropy change
C.) positive enthalpy change and negative entropy change
D.) negative enthalpy change and positive entropy change
Answers
Answer: B.) negative enthalpy change and negative entropy change
Explanation:
According to Gibb's equation:
= Gibbs free energy
= enthalpy change
= entropy change
T = temperature in Kelvin
= +ve, reaction is non spontaneous
= -ve, reaction is spontaneous
= 0, reaction is in equilibrium
Thus when = -ve
= -ve
only at low temperature
Reaction is spontaneous only if temperature is low.
since the formula G=H-TS when a reaction is spontaneous then G must be negative, and if values of t are low then the only time it is guaranteed to be a negative G value is if H is positive and S is negative
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2K₃PO₄ + 3NiCl₂ ---> 6KCl + Ni₃(PO₄)₂
stoichiometry of K₃PO₄ to NiCl₂ is 2:3
the number of NiCl₂ moles reacted - 0.0110 mol/L x 0.154 L = 1.69 x 10⁻³ mol
if 3 mol of NiCl₂ reacts with - 2 mol of K₃PO₄
then 1.69 x 10⁻³ mol of NiCl₂ reacts with - 2/3 x 1.69 x 10⁻³ = 1.13 x 10⁻³ mol of K₃PO₄
molarity of K₃PO₄ solution given - 0.205 M
there are 0.205 mol in 1 L
therefore 1.13 x 10⁻³ mol are in - 1.13 x 10⁻³ mol / 0.205 mol/L = 5.51 mL
volume of K₃PO₄ required - 5.51 mL
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b) Ionic compounds represent high temperature melting and boiling.
c) They are hard and brittle and then subjected to the impact, break easily, creating planar faces.
d) When dissolved in water, or pure liquid, carry electrical current due to the existence of ions that move freely and can be attracted by the electrodes, closing the electric circuit.
e) His solvent is water.
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a comment
a planet
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Answer:
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Explanation:
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