Answer:
This means the the sign of q for the reaction was _NEGATIVE _____ and the reaction was _EXOTHERMIC_____.
Explanation:
In calorimetry, when heat is absorbed by the solution, the q-value of the solution will have a positive value. This means that the reaction will produce heat for the solution to absorb and thus the q-value for the reaction will be negative. This is an exothermic reaction.
Whereas, when heat is absorbed from the solution, the q-value for the solution will have a negative value. This means that the reaction will absorb heat from the solution and so the reaction is endothermic, and q value for the reaction is positive.
So, from the question, since the q-value of water is positive, it means that heat is absorbed by the solution and the reaction will produce a negative value of q and it's an exothermic reaction because the reaction produces heat for the solution.
Answer:
Part one: B. Kc decreases
Part two: B. Is equal to Kc
Part three: B. Run in the reverse direction to reestablish equilibrium
Part four: A. Increase
Explanation:
Part one: Sulfur dioxide combines with oxygen to form sulphur trioxide in an exothermic reaction. If the temperature is suddenly is increased, while the reaction is at equilibrium, the backward reaction (the endothermic one) is favored to "sweep up the excess heat". An increase in reactants means a decrease in Kc since the denominator(reactants) is becoming bigger while the numerator (products) become smaller.
Part two: Qc is a varying version of Kc. For this set of circumstances, it will be equal to Kc since Kc varies with temperature
Part three: The reaction must run in the reverse to reestablish the equilibrium.
Part four: The concentration of of oxygen will increase as more of the reactants are formed
The increase in temperature for this exothermic reaction will cause the value of Kc to decrease, the value of Qc to be greater than Kc, the reaction to run in the reverse direction, and the concentration of O2 to increase.
The given chemical reaction represents a type of equilibrium reaction, specifically an exothermic reaction, as it produces sulfur trioxide (SO3), which releases heat. According to Le Chatelier's principle, to maintain equilibrium, if a system is disturbed by an external factor, the system will adjust accordingly.
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Answer:
The mixture is not in equilibrium, the reaction will shift to the left.
Explanation:
Based on the equilibrium:
Fe³⁺+ HSCN ⇄ FeSCN²⁺ + H⁺
kc = 30 = [FeSCN²⁺] [H⁺] / [Fe³⁺] [HSCN]
Where [] are concentrations at equilibrium. The reaction is in equilibrium when the ratio of concentrations = kc
Q is the same expression than kc but with [] that are not in equilibrium
Replacing:
Q = [10.0M] [1.0M] / [0.1M] [0.1M]
Q = 1000
As Q > kc, the reaction will shift to the left in order to produce Fe³⁺ and HSCN untill Q = Kc
The mixture's equilibrium status can be determined by comparing the reaction quotient (Q) with the equilibrium constant (Kc). If Q < Kc, the reaction proceeds to the right (products) to achieve equilibrium. If Q > Kc, the reaction proceeds to the left (reactants) to achieve equilibrium.
To determine if the mixture is initially at equilibrium, we need to calculate and compare the reaction quotient (Q) and the equilibrium constant (Kc) of the reaction. The reaction quotient is a measure of the relative concentrations of products and reactants at any point in time, whereas Kc, is the measure of these concentrations only at equilibrium.
Assuming that the reaction in question is: Fe3+ + HSCN ↔ FeSCN2+ + H + . In this case,
Q = [FeSCN2+]/[Fe3+][HSCN] = 10 / (0.1 * 0.1) = 1000. If Kc is less than 1000, the reaction is not at equilibrium and will need to proceed to the left (reactants) to reach equilibrium. Conversely, if Kc is greater than 1000, the reaction is not at equilibrium and will need to proceed to the right (products).
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Answer:
The correct option is: B) H₂0 and OH⁻ as a conjugate pair
Explanation:
According to Brønsted-Lowry theory, theacids are the chemical substances that form a conjugate base by donating a proton and bases are the chemical substances that form conjugate acid by accepting a proton.
In the given chemical reaction: PO₄³⁻(aq) + H₂O(l) ⇄ HPO₄²⁻(aq) + OH⁻(aq)
According to Brønsted-Lowry theory, PO₄³⁻ and OH⁻ are bases. Whereas, H₂O and HPO₄²⁻ are acids.
Also, PO₄³⁻ and HPO₄²⁻ are the conjugate acid-base pair; and H₂O and OH⁻ are the conjugate acid-base pair.
Determine the amount of CO2(g) formed in the reaction if 8.00 grams of O2(g) reacts with an excess of C2H6(g) and the percent yield of CO2(g) is 90.0%.
Answer: The amount of carbon dioxide formed in the reaction is 5.663 grams
Explanation:
To calculate the number of moles, we use the equation:
.....(1)
Given mass of oxygen gas = 8 g
Molar mass of oxygen gas = 32 g/mol
Putting values in equation 1, we get:
For the given chemical equation:
By Stoichiometry of the reaction:
7 moles of oxygen gas produces 4 moles of carbon dioxide
So, 0.25 moles of oxygen gas will produce = of carbon dioxide
Now, calculating the mass of carbon dioxide from equation 1, we get:
Molar mass of carbon dioxide = 44 g/mol
Moles of carbon dioxide = 0.143 moles
Putting values in equation 1, we get:
To calculate the experimental yield of carbon dioxide, we use the equation:
Percentage yield of carbon dioxide = 90 %
Theoretical yield of carbon dioxide = 6.292 g
Putting values in above equation, we get:
Hence, the amount of carbon dioxide formed in the reaction is 5.663 grams
B. Diethyl ether, dichloromethane, ethyl acetate, ethanol
C. Ethyl acetate, ethanol, dichloromethane, diethyl ether
D. Ethanol, ethyl acetate, diethyl ether, dichloromethane
Answer:
B. Diethyl ether, dichloromethane, ethyl acetate, ethanol
Explanation:
The polarity of solvents can be determined by their polarity indexes. Polarity index is defined as the measure of the ability of the solvent to interact with various polar test solutes.
Diethyl ether is the least polar with a polarity index of 2.8
Dichloromethane with a polarity index of 3.1
Ethyl acetate with a polarity index of 4.3
Ethanol is the most polar with a polarity index of 5.2
The differences in polarities of these solvents is due to their structure. Polar solvents have large dipole moments because they contain bonds between atoms with very different electronegativities, such as oxygen and hydrogen.
Because of the two non-polar methyl groups in diethyl ether, it is not as polar as dichloromethane which has two electronegative chlorine atoms attached to a carbon atom. Similarly too, because diethyl ether has two strongly electronegative oxygen atoms sharing a bond with carbon, it has a larger dipole moment than dichloromethane. Ethanol has an oxygen hydrogen bond which has the largest dipole moment, thus, it is the most polar of the given solvents.
(b) Calculate the mass of ammonia produced when 35.0g of nitrogen reacts with hydrogen.
Answer:
a) N2 (g) + H2 = 2 NH3
b) You have to state the mass of hydrogen