A student dissolved 1.805g of a monoacidic weak base in 55mL of water. Calculate the equilibrium pH for the weak monoacidic base (B) solution. Show all your work.pKb for the weak base = 4.82.

Molar mass of the weak base = 82.0343g/mole.

Note: pKa = -logKa

pKb = -logKb

pH + pOH = 14

[H+ ] [OH- ] = 10^-14

Answers

Answer 1
Answer:

Answer:

11.39

Explanation:

Given that:

pK_(b)=4.82

K_(b)=10^(-4.82)=1.5136* 10^(-5)

Given that:

Mass = 1.805 g

Molar mass = 82.0343 g/mol

The formula for the calculation of moles is shown below:

moles = (Mass\ taken)/(Molar\ mass)

Thus,

Moles= (1.805\ g)/(82.0343\ g/mol)

Moles= 0.022\ moles

Given Volume = 55 mL = 0.055 L ( 1 mL = 0.001 L)

Molarity=(Moles\ of\ solute)/(Volume\ of\ the\ solution)

Molarity=(0.022)/(0.055)

Concentration = 0.4 M

Consider the ICE take for the dissociation of the base as:

                                  B +   H₂O    ⇄     BH⁺ +        OH⁻

At t=0                        0.4                          -              -

At t =equilibrium     (0.4-x)                        x           x            

The expression for dissociation constant is:

K_(b)=\frac {\left [ BH^(+) \right ]\left [ {OH}^- \right ]}{[B]}

1.5136* 10^(-5)=\frac {x^2}{0.4-x}

x is very small, so (0.4 - x) ≅ 0.4

Solving for x, we get:

x = 2.4606×10⁻³  M

pOH = -log[OH⁻] = -log(2.4606×10⁻³) = 2.61

pH = 14 - pOH = 14 - 2.61 = 11.39


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Answers

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Answers

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Answers

Answer:

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Hello,

In this case, since the van't Hoff factor is related with the species that result from the ionization of a chemical compound, we can see that that

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- Ammonium nitrate NH4NO3 dissociates in one ammonium ions and one nitrate ion, therefore, van't Hoff factor is 2 (correct).

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Best regards.

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Answers

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