A 0.5-m3 rigid tank contains refrigerant-134a initially at 200 kPa and 40 percent quality. Heat is transferred now to the refrigerant from a source at 358C until the pressure rises to 400 kPa. Determine (a) the entropy change of the refrigerant, (b) the entropy change of the heat source, and (c) the total entropy change for this process.

Answers

Answer 1
Answer:

Answer:

(a) \Delta S_(ref)=3.876(kJ)/(K)

(b) S_(heat\ source)=-1.678(kJ)/(K)

(c) \Delta S _(tot)=2.198(kJ)/(K)

Explanation:

Hello,

(a) In this case, such refrigerant, we can notice that at the given conditions, the initial entropy from property tables (Cengel 7th ed) is:

s_(initial)=s_f+xs_(fg)=0.15457+0.4*0.78316=0.4678(kJ)/(kg*K)

Now, for the final condition, we first need to compute the initial specific volume as it remains the same (rigid tank) after the thermodynamic process:

v_(initial)=v_f+xv_(fg)=0.0007533+0.4*(0.099867-0.0007533)=0.0404(m^3)/(kg)

Then, at 400 kPa we evaluate the given volume that is also between the liquid and vapor specific volume, thus, we calculate the quality at the end of the process:

x_f=(0.0404-0.0007907)/(0.051201-0.0007907) =0.786

With it, we compute the final entropy:

s_(final)=0.24761+0.785*0.67929=0.781(kJ)/(kg*K)

Finally, entropy change for the refrigerant turns out:

m_(ref)=(0.5m^3)/(0.0404(m^3)/(kg) )=12.4kg \n\n\Delta S_(ref)=12.4kg *(0.781(kJ)/(kg*K)-0.4678(kJ)/(kg*K) )\n\n\Delta S_(ref)=3.876(kJ)/(K)

(b) In this case, by using the first law of thermodynamics we compute the acquired heat by the refrigerant from the heat source by computing the initial and final internal energy respectively (no work is done):

Q=\Delta U

u_(initial)=38.28+0.4*186.21=112.764(kJ)/(kg)\n \nu_(final)=63.62+0.786*171.45=198.40(kJ)/(kg)

Hence:

Q=12.4kg*(198.40-112.764)(kJ)/(kg) =1059.1kJ

Finally, the entropy change of the heat source (which release the heat, therefore it is negative):

S_(heat\ source)=(1059.1kJ )/((358+273.15)K) \n\nS_(heat\ source)=-1.678(kJ)/(K)

(c) Then, the total entropy change or the entropy generation for the process is:

\Delta S _(tot)=3.876(kJ)/(K)-1.678(kJ)/(K)\n\n\Delta S _(tot)=2.198(kJ)/(K)

Which has thermodynamic agreement as it is positive

Regards.

Answer 2
Answer:

Final answer:

The entropy changes in this process can be partially calculated using principles from thermodynamics. However, without the exact heat transfer, not all values can be determined.

Explanation:

The calculation of the entropy change in this thermodynamic process involves principles from thermodynamics and requires steps to determine the initial and final states of the refrigerant. First, we would need to find the entropy at the initial and final states using the refrigerant properties table for refrigerant-134a and the provided information (200 kPa and 40% quality initially, 400 kPa finally). The entropy change of the refrigerant is the difference between the final and initial entropy.

Next, the entropy change of the heat source is calculated as the heat transfer divided by the absolute temperature of the source. However, the problem does not provide the amount of heat transferred from the source, making it impossible to determine this value directly.

Finally, in an isolated system, the total entropy change of the process is the sum of the entropy changes of the refrigerant and the heat source. Here, the precise values cannot be calculated due to a lack of specific data including exact heat transfer.

Learn more about Entropy Change here:

brainly.com/question/35154911

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Show the conversion factor from Patolbf/ft2is 0.02089.

Answers

Explanation:

1 Pascal = 1 N/m²

To convert Pa to lbf/ft²

So, the conversion of N to pound force (lbf) is shown below as:

1 N = 0.224809 pound force (lbf)

The conversion of m² to ft² is shown below:

1 m² = 10.7639 ft²

So,

[tex]1\ Pa=\frac {1\ N}{1\ m^2}=\frac {0.224809\ lbf}{10.7639\ ft^2}

1 Pa = 0.02089 lbf / ft²

Hence proved.

A chemist prepares hydrogen fluoride by means of the following reaction:CaF2 + H2SO4 --> CaSO4 + 2HF

The chemist uses 11 g of CaF2 and an excess of H2SO4, and the reaction produces 2.2 g of HF.
(a) Calculate the theoretical yield of HF.

(b) Calculate the percent yield of HF.

Answers

Answer:

39.3%

Explanation:

CaF2 + H2SO4 --> CaSO4 + 2HF

We must first determine the limiting reactant, the limiting reactant is the reactant that yields the least number of moles of products. The question explicitly says that H2SO4 is in excess so CaF2 is the limiting reactant hence:

For CaF2;

Number of moles reacted= mass/molar mass

Molar mass of CaF2= 78.07 g/mol

Number of moles reacted= 11g/78.07 g/mol = 0.14 moles of Calcium flouride

Since 1 mole of calcium fluoride yields two moles of 2 moles hydrogen fluoride

0.14 moles of calcium fluoride will yield 0.14×2= 0.28 moles of hydrogen fluoride

Mass of hydrogen fluoride formed (theoretical yield) = number of moles× molar mass

Molar mass of hydrogen fluoride= 20.01 g/mol

Mass of HF= 0.28 moles × 20.01 g/mol= 5.6 g ( theoretical yield of HF)

Actual yield of HF was given in the question as 2.2g

% yield of HF= actual yield/ theoretical yield ×100

%yield of HF= 2.2/5.6 ×100

% yield of HF= 39.3%

A sample containing only carbon, hydrogen, and silicon is subjected to elemental analysis. After complete combustion, a 0.7020 g sample of the compound yields 1.4 g of CO2, 0.86 g of H2O, and 0.478 g of SiO2. What is the empirical formula of the compound?

Answers

Answer: The empirical formula of compound is C_4H_(12)Si.

Explanation:

Mass of Sample= 0.702 g

Mass of CO_2 = 1.4 g

Mass of H_2O = 0.86 g

Mass of SiO_2 = 0.478 g  

First we have to calculate moles ofCO_2, H_2O and SiO_2 formed.

1. Moles of CO_2=(1.4g)/(44g/mol)=0.032mol

Now , Moles of carbon == Moles of CO_2 = 0.032

2.  Moles of H_2O=(0.86g)/(18g/mol)=0.048mol​​​

Now , Moles of hydrogen = 2* Moles of H_2O =2* 0.048=0.096mol

3.  Moles of SiO_2=(0.478g)/(60g/mol)=0.008 mol

Now , Moles of silicon = Moles of SiO_2 = 0.008 moles

Therefore, the ratio of number of moles of C : H : Si is  = 0.032 : 0.096 : 0.008

For the mole ratio, divide each value of moles by the smallest number of moles calculated.

For C= (0.032)/(0.008)=4

For H =(0.096)/(0.008)=12

For Si=(0.008)/(0.008)=1

Thus, C: H: Si = 4 : 12 : 1

The simplest ratio represent empirical formula.

Hence, the empirical formula of compound is C_4H_(12)Si.

“the density of a subtance generally decreases as the temperature increases”

Answers

Answer:

The correct answer is D.

Explanation:

Water can evaporate, and if it does, the density decreases

After 56.0 min, 40.0% of a compound has decomposed. What is the half‑life of this reaction assuming first‑order kinetics?

Answers

Answer:

Go ahead and plug in the percentages and time to find the answer.

Explanation:

The amount of a substance with half-life h, that remains after time t is 0.5t/h

 

Since 26% has decomposed, 74% remains.

 

So .74 = 0.580/h

 

ln .74 = (80/h) ln 0.5

 

h/80 = ln 0.5 / ln .74

 

h = 80 ln 0.5 / ln .74

 

h = 184.16 minutes

4.What volume of 0.120 M HNO3(aq) is needed to
completely neutralize 150.0 milliliters of 0.100 M
NaOH(aq)?
A. 62.5 mL
B. 125 ml
C.
180. mL
D. 360. mL

Answers

Answer:

B) 125 mL

Explanation:

M1V1=M2V2

(0.120M)(x)=(150.0 mL)(0.100M)

x= 125 mL

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