What substance is used in the industrial preparation of methyl diantilis to reduce the aldehyde group of 3-ethoxy-4-hydroxybenzaldehyde?

Answers

Answer 1
Answer:

The substance that is used for the industrial preparation of methyl diantilis is called the sodium borohydride (NaBH4).

Industrial preparation of methyl diantilis:

Methyl diantilis is a substance that has an elegant fragrance with a similar olfactive note to Isoeugenol.

It is used as complexing agent for vanilla, tobacco, leather and fruit accords.

It can be prepared industrially by the reduction of 3-ethoxy-4-hydroxybenzaldehyde (ethyl vanillin) to 3-ethoxy-4-hydroxybenzyl alcohol.

To reduce the aldehyde group of 3-ethoxy-4-hydroxybenzaldehyde, sodium borohydride is added in the industrial preparation process.

The sodium borohydride (NaBH4) produces a phenol functional group with other reactants leading to reduction of aldehyde group and increase in the solubility of reactants.

Therefore, the substance that is used for the industrial preparation of methyl diantilis is called the sodium borohydride (NaBH4).

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Answer 2
Answer:

Answer:

            Sodium Borohydride (NaBH₄)

Explanation:

                    Methyl diantilis (2-Ethoxy-4-(methoxymethyl)phenol) is a fragrance compound which smells like Vanilla. This compound is being synthesized from 3-ethoxy-4-hydroxybenzaldehyde also known as Ethyl Vanillin in two steps.

Step 1: Reduction of Aldehydic Group on Ethyl Vanillin:

The benzaldehyde derivative is treated with a mild reducing agent i.e. NaBH₄ (Sodium Borohydride). NaBH₄ is a source of Hydride (H⁻) ion and undergoes nucleophilic substitution reaction yielding 2-ethoxy-4-(hydroxymethyl)phenol.

Step 2: Etherification of 2-ethoxy-4-(hydroxymethyl)phenol:

In the second step 2-ethoxy-4-(hydroxymethyl)phenol is treated with Methanol in the presence of strong acidic polymeric resin known as Amberlyst-15-wet resulting in the formation of Methyl diantilis as shown in attached figure.


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What is the speed of a basketball that is thrown 18meters in 4 seconds?

Answers

Answer:

4.5m/s

Explanation:

speed = distance/time

speed = 18/4

speed = 4.5m/s

The Michael reaction is a conjugate addition process wherein a nucleophilic enolate anion (the donor) reacts with an α,β-unsaturated carbonyl compound (the acceptor). The best Michael reactions are those that take place when a particularly stable enolate anion is formed via treatment of the donor with a strong base. Alternatively, milder conditions can be used if an enamine is chosen as the donor, this variant is termed the Stork reaction. In the second step, the donor adds to the β-carbon of the acceptor in a conjugate addition, generating a new enolate. The enolate abstracts a proton from solvent or from a new donor molecule to give the conjugate addition product. Draw curved arrows to show the movement of electrons in this step of the mechanism.

Answers

Answer:

See the attached file for the structure

Explanation:

See the attached file

Scaled Synthesis of Alum. Show your calculations for:a.the experimental scaling factor giving rise to a 15.0 g theoretical yield;b.the corrected volumes of KOH and H2SO4; andc.the theoretical yield of alum based on the actual amount of Al used.Make sure you carefully show each step for these calculations.

Answers

Answer:

(c) 18.8 g; (a) 0.798; (b) 16 mL

Explanation:

You don't give your experimental data, so I shall assume:

Mass of Al = 1.07 g

20 mL of 3 mol·L⁻¹ KOH

20 mL of 9 mol·L⁻¹ H₂SO₄

The overall equation for the reaction is

Mᵣ:    26.98                                                              474.39

          2Al + 2KOH +4H₂SO₄ + 22H₂O ⟶ 2K[Al(SO₄)₂]·12H₂O + 3H₂

m/g:   1.07

(c) Theoretical yield of alum

(i) Moles of Al

\text{Moles of Al} = \text{1.07 g Al} * \frac{\text{1 mol Al}}{\text{26.98 g Al}} = \text{0.039 66 mol Al}

(ii) Moles of alum

\text{Moles of alum} = \text{0.039 66 mol Al} * \frac{\text{2 mol alum }}{\text{2 mol Al}} = \text{0.039 66 mol alum \n}

(iii) Theoretical yield of alum

\text{Mass of alum} = \text{0.039 66 mol alum} * \frac{\text{474.39 g alum}}{\text{1 mol alum}} = \textbf{18.8 g alum}

(a) Scaling factor for 15.0 g alum

You want a theoretical yield of 15.0 g, so you must scale down the reaction.

\text{Scale factor} = (15.0)/(18.8) = \mathbf{0.798}

(b) Corrected volumes of NaOH and H₂SO₄

V = 0.798 × 20 mL = 16 mL

Which isomer would you expect to undergo E2 elimination faster, trans-1-bromo-4-tert-butylcyclohexane or cis-1-bromo-4-tert-butylcyclohexane? Draw each molecule in its more stable chair conformation, and explain your answer.

Answers

Answer: Cis-1-bromo-4-tert-butylcyclohexane would undergo faster elimination reaction.

Explanation:

The two primary requirements for an E-2 elimination reaction are:

1.There must be availability of β-hydrogens that is presence of hydrogen on the carbon next to the leaving group.

2.The hydrogen and leaving group must have a anti-periplanar position .

Any substrate which would follow the above two requirements can give elimination reactions.

For the structure of trans-1-bromo-4-tert-butylcyclohexane and cis-1-bromo-4-tert-butylcyclohexane  to be stable it  must have the tert-butyl group in the equatorial position as it is a bulky group and at equatorial position it would not repel other groups. If it is kept on the axial position it would undergo 1,3-diaxial interaction and would destabilize the system and that structure would be unstable.

Kindly find the structures of trans-1-bromo-4-tert-butylcyclohexane and cis-1-bromo-4-tert-butylcyclohexane in attachment.

The cis- 1-bromo-4-tert-butylcyclohexane has the leaving group and β hydrogens in anti-periplanar position so they can give the E2 elimination reactions easily.

The trans-1-bromo-4-tert-butylcyclohexane  does not have the leaving group and βhydrogen in anti periplanar position so they would not give elimination reaction easily.

so only the cis-1-bromo-4-tert butyl cyclohexane would give elimination reaction.

Final answer:

Trans-1-bromo-4-tert-butylcyclohexane is expected to undergo E2 elimination faster than cis-1-bromo-4-tert-butylcyclohexane due to less steric hindrance.

Explanation:

In determining the rate of E2 elimination, the trans-1-bromo-4-tert-butylcyclohexane would undergo E2 elimination faster than the cis-1-bromo-4-tert-butylcyclohexane. This is due to the larger degree of steric hindrance in the case of the cis isomer.

In trans-1-bromo-4-tert-butylcyclohexane, the bromine is at the equatorial position while the tert-butyl group is axial. It forms a structure that allows the compound to experience less steric hindrance with bromine in a more favorable position for leaving.

In comparison, cis-1-bromo-4-tert-butylcyclohexane has a bromine and tert-butyl group both at equatorial positions. This causes steric hindrance, and in turn, slows down the E2 elimination rate. Despite the more stable conformation, the bromine is not well-oriented for a leaving group in E2 elimination.

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Be sure to answer all parts.Calculate the percent composition by mass (to 4 significant figures) of all the elements in calcium
phosphate (Ca3(PO4)2), a major component of bone.
% Ca
%P
% 0​

Answers

Answer:

38.7%

41.3%

20%

Explanation:

The percentage composition helps to know the what percent of the total mass of a compound is made up of each of the constituent elements or groups.

To solve this problem:

  • find the formula mass by adding the atomic masses of the atoms that makes up the compound.
  • place the mass contribution of the element or group to the formula mas and multiply by 100;

Compound:

 Ca₃(PO₄)₂

  Formula mass = 3(40) + 2[31 + 4(16)]

                           = 120 + 2(95)

                           = 120 + 190

                           = 310

%C = (3(40))/(310) x 100  = 38.7%

%P = (8(16))/(310) x 100  = 41.3%

%O = (2(31))/(310) x 200  = 20%

What is the name of the structures that help move substances across a tract surface?

Answers

Answer:

cilia and flagella

Explanation:

In prokaryotic species , cilia are present , and in eukaryotic species , flagella is present .

Cilia and flagella both have same function , i.e. , to enable the movement of the cell , along with the movement of some substance and direct the flow of these substance along the tracts.

Cilia and flagella are composed of basal bodies.

Hence , from the given statement of the question,

The correct term is cilia and flagella .

Final answer:

Cilia are the structures that help move substances across the surface of a tract. They are primarily found in certain types of cells such as those in the respiratory tract and the oviducts.

Explanation:

The structures that assist in moving substances across a tract surface are primarily called cilia. In biology, cilia are tiny hair-like structures that line certain types of cells, especially those in the respiratory tract and the oviducts. They work much like oars on a boat, moving in coordinated waves to propel substances (like mucus or egg cells) along the surface of the tract they occupy. They are responsible in movement of substances across tract.

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